Studies of the hyperfine structure (hfs) and M1–E2 interference effect in the Zeeman spectra of two mixed-type M1+E2 forbidden lines: 541.5 nm and 609.8 nm of antimony are reported. Experiments were performed with two stable isotopes of antimony: 121 and 123. By the use of a computer modelling technique the simulated contours were fitted to the recorded spectra. Our experiment yields hfs constants for levels 2P1/2 and 2P3/2 of ground configuration 5s25p3 for isotope 121: A(2P1/2) = 165.6(0.24) mK, A(2P3/2) = 22.69(0.05) mK, B(2P3/2) = 16.1(0.4) mK and for isotope 123: A(2P1/2) = 88.19(0.08) mK, A(2P3/2) = 12.44(0.05) mK and B(2P3/2) = 26.8(0.4) mK. Study of the interference effect carried out for the line 541.5 nm at several magnetic fields leads to an extremely small E2 admixture, <0.002% for isotope 121 and (0.003 ± 0.001)% for isotope 123. The experiment carried out for the line 609.8 nm yields the E2 admixtures: (0.2 ± 0.1)% for isotope 121 and (0.5 ± 0.2)% for isotope 123.