1986
DOI: 10.1017/s0022112086000332
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The dynamics of the spreading of liquids on a solid surface. Part 1. Viscous flow

Abstract: An investigation is made into the dynamics involved in the movement of the contact line when one liquid displaces an immiscible second liquid where both are in contact with a smooth solid surface. In order to remove the stress singularity at the contact line, it has been postulated that slip between the liquid and the solid or some other mechanism must occur very close to the contact line. The general procedure for solution is described for a general model for such slip and also for a general geometry of the s… Show more

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Cited by 1,262 publications
(1,242 citation statements)
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References 23 publications
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“…(13) is valid only for finite-thickness interfaces and implies a surface-force singularity if the interface thickness tends to zero. To eliminate the singularity the dynamic and static contact angles should be equal α = α ′ , which explains the underlying reason of Cox's hypothesis [4] for a macroscopic analysis stating that wall-slip is permitted and the contact angle is independent of contact-line velocity. A result of the surface-force balance with α = α ′ from Eq.…”
Section: Discussionmentioning
confidence: 99%
“…(13) is valid only for finite-thickness interfaces and implies a surface-force singularity if the interface thickness tends to zero. To eliminate the singularity the dynamic and static contact angles should be equal α = α ′ , which explains the underlying reason of Cox's hypothesis [4] for a macroscopic analysis stating that wall-slip is permitted and the contact angle is independent of contact-line velocity. A result of the surface-force balance with α = α ′ from Eq.…”
Section: Discussionmentioning
confidence: 99%
“…[1][2][3] The theories of spreading can be divided into two groups in which the main difference is the identification of the primary source of energy dissipation that controls the movement of the liquid front. [3][4][5][6][7] Continuous hydrodynamic theories focus on spreading controlled by the bulk liquid's viscous impedance 5,[8][9][10] while molecularkinetic analyses describe a situation in which local dissipation at the triple line is the dominant contribution. 4,6,11,12 The relative importance of each dissipation mechanism depends on a balance between the viscosity, the activation energy for viscous flow, and the strength of the solid/liquid interactions.…”
Section: Introductionmentioning
confidence: 99%
“…Hydrodynamic theories search for a universal relationship between the dynamic contact angle and the capillary number, Ca = vη/γ lv (v is the velocity of the triple junction and η the liquid viscosity), that is typically written in the form [8][9][10] :…”
mentioning
confidence: 99%
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“…In the first group, the bouncing process and the number of bouncing adopted; the hydrodynamic model (Cox, 1986), and the molecular kinetic does not increase strongly leading the author to suggest that the bouncing 100 process is not entirely controlled by flow properties in the liquid film. Most…”
mentioning
confidence: 99%