Light emission studies of the ,high-field conduction and prebreakdown phenomena in a mixture of mono and dibenzyltoluene (M/DBT), used as polypropylene impregnant in the all-film capacitor technology, have been undertaken t o gain insight into the underlying physical mechanisms responsible for these processes. The absorption spectrum of this fluid, in the U V region, shows the appearance of structured bands at 348, 366 and 386 nm indicating a luminescence process via anthracene and 9-met hylant hracene impurities at a concentration of 3~1 0 -~ mol/l. Optical and electrical measurements were performed simultaneously on the electrically stressed fluid. Electroluminescence of the impurities contained in M/DBT has been investigated using a new uniform field electrode arrangement. The light inception stress was determined t o be -20 Vpm-' for ac excitation (50 Hz). Configurations with different interfacial situations were studied and we have evidenced a correlation between charge injection and electroluminescence activity. Spectral analysis of the light radiated by streamers in M/DBT in a needle-plane electrode geometry, under step voltage (1 t o 50 ps, 30 kV) revealed, for both polarities, the presence of H1 and Ca characteristic bands emerging from a continuum corresponding to the dissociation and recombination of molecular fragments.