The Dynamic Chemistry of Orthoesters and Trialkoxysilanes: Making Supramolecular Hosts Adaptive, Fluxional, and Degradable

Hollstein, Selina; von Delius, Max

doi:10.1021/acs.accounts.3c00738

Cited by 1 publication

(1 citation statement)

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“…Silicon-containing polymeric materials have received much attention in organic and material chemistry due to their various industrial and academic applications [1][2][3][4][5][6][7]. Based on the silicon linkages of the main chains, these materials can be classified into several major types (Scheme 1).…”

Section: Introductionmentioning

confidence: 99%

Poly(silyl ether)s as Degradable and Sustainable Materials: Synthesis and Applications

Zotov,

Vijjamarri,

Mousavi

et al. 2024

Molecules

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Polymer research is currently focused on sustainable and degradable polymers which are cheap, easy to synthesize, and environmentally friendly. Silicon-based polymers are thermally stable and can be utilized in various applications, such as columns and coatings. Poly(silyl ether)s (PSEs) are an interesting class of silicon-based polymers that are easily hydrolyzed in either acidic or basic conditions due to the presence of the silyl ether Si-O-C bond. Synthetically, these polymers can be formed in several different ways, and the most effective and environmentally friendly synthesis is dehydrogenative cross coupling, where the byproduct is H2 gas. These polymers have a lot of promise in the polymeric materials field due to their sustainability, thermal stability, hydrolytic degradability, and ease of synthesis, with nontoxic byproducts. In this review, we will summarize the synthetic approaches for the PSEs in the recent literature, followed by the properties and applications of these materials. A conclusion and perspective will be provided at the end.

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Section: Introductionmentioning

confidence: 99%

Poly(silyl ether)s as Degradable and Sustainable Materials: Synthesis and Applications

Zotov,

Vijjamarri,

Mousavi

et al. 2024

Molecules

View full text Add to dashboard Cite

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The Dynamic Chemistry of Orthoesters and Trialkoxysilanes: Making Supramolecular Hosts Adaptive, Fluxional, and Degradable

Abstract: We show that cryptates assembled from orthoester bridgeheads and urea-diols are capable of encapsulating biologically relevant anions, as well as cesium chloride.

Cited by 1 publication

References 57 publications

Poly(silyl ether)s as Degradable and Sustainable Materials: Synthesis and Applications

Poly(silyl ether)s as Degradable and Sustainable Materials: Synthesis and Applications

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