The dominant steric effect in the synthesis of ammine hydrido- and chlorido-Ru(II)- N , N -dimethylhydrazine and mixed alkyl–aryl phosphine complexes: Novel methyldiazene reduction intermediates

Structural, Electrochemical and Catalytic Elucidation of Cyclooctadiene Ru(II)‐Nitrile Complexes of the Type [RuCl2(cod)(NCR)2]

“…Ruthenium‐based complexes are known to be catalytically active in an impressive range of C−H, [19,20] C−C, [19–21] C−N, [21–23] C−O, [21,23] C‐halogen, [20b] N−N, [24,25] N−H, [20,26] O−O, [27,28] O−H, [20,28] N−O, [29] C−S, [30] S−S, [31] C‐Si [28] and C‐B [32] transformation reactions. However, no information on the catalytic activity of the Ru‐nitrile complexes investigated in this study exists.…”

“…Ruthenium-based complexes are known to be catalytically active in an impressive range of CÀ H, [19,20] CÀ C, [19][20][21] CÀ N, [21][22][23] CÀ O, [21,23] C-halogen, [20b] NÀ N, [24,25] NÀ H, [20,26] OÀ O, [27,28] OÀ H, [20,28] NÀ O, [29] CÀ S, [30] SÀ S, [31] C-Si [28] and C-B [32] transformation reac-…”