1990
DOI: 10.1016/0009-2614(90)80025-9
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The diode laser spectrum of three isotopic forms of PbH in its 2Π12 ground state

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Cited by 11 publications
(7 citation statements)
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“…The latter finding reflects the fact that the X 2 potential curve dissociates into a fine structure component of the lead atom lying 7819 cm À1 higher than that correlated with the X 1 1/2 state (Pb( 3 P 1 ) + H( 2 S 1/2 ) vs. Pb( 3 P 0 ) + H( 2 S 1/2 )) [4]. The rotational constants of X 1 are found to be in good agreement with the results of Magg and Jones [5] (Table 7), the small differences in some parameters likely are due to the fact that these authors used some additional higher order terms in their analyses.…”
Section: Discussionsupporting
confidence: 83%
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“…The latter finding reflects the fact that the X 2 potential curve dissociates into a fine structure component of the lead atom lying 7819 cm À1 higher than that correlated with the X 1 1/2 state (Pb( 3 P 1 ) + H( 2 S 1/2 ) vs. Pb( 3 P 0 ) + H( 2 S 1/2 )) [4]. The rotational constants of X 1 are found to be in good agreement with the results of Magg and Jones [5] (Table 7), the small differences in some parameters likely are due to the fact that these authors used some additional higher order terms in their analyses.…”
Section: Discussionsupporting
confidence: 83%
“…6.0(4) 0.82 (9) 10 6 a p3/2 À2.6(5) À0.08 (8) r e (Å) 1.83929 (2) 1.81719 (2) 1.838335 (12) 1.817021 (12) a Numbers in parentheses are the statistical error limits in units of the last digit. b Numbers in italics are the results of Magg and Jones [5] given for comparison.…”
Section: Discussionmentioning
confidence: 99%
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“…The example of the indium hydride complex illustrates too that hydride ligands bound to maingroup metals do not generally share with those bound to transition metals the property of resonating at a distinctively low frequency. 2 The quadrupolar character of several of the key metal nuclei (e.g., 27 Al, 69 Ga, and 71 Ga) has also impaired the usefulness of these nuclei as NMR probes for hydride derivatives of the relevant metals in any but the most sym-metrical environments (e.g., AlH 4and GaH 4 -). 153,193,194 Systems which have attracted spectroscopic investigation, frequently together with colligative measurements, include ether solutions of the following species: (i) the magnesium hydrides RMgH, RMg 2 H 3 , and HMgX (R ) Me, Et, Pr i , Ph, or Cp; 195 X ) Cl or Br 196 ); (ii) AlH 3 ; 197 and (iii) the bi-and trimetallic species LiMgH 2 R, 15 LiMg 2 H 3 R 2 , 15 Li 2 MgH 2 R 2 , 15 HMg-MH 4 (M ) B or Al), 196,198 Mg(AlH 4 )(BH 4 ), 196,198 LiZnMe 2 AlH 4 , 199 and LiZn 2 Me 4 AlH 4 .…”
Section: The Condensed Phases: Diffraction Of Crystalline Solids and ...mentioning
confidence: 99%
“…As yet, however, no lead(IV) hydride has yielded to structural authentication and experiment gives no guide to the dimensions of PbH n units, with the single exception of the gaseous PbH radical. 27…”
Section: The Group 14 Metalsmentioning
confidence: 99%