Shale oil/gas is a type of unconventional energy and
an important
supplement to the energy structure worldwide. Hydraulic fracturing
plays a necessary role in exploiting this kind of resource, and a
higher salt ion concentration exists in flowback fluid, which is totally
different from conventional reservoirs. To understand the special
mechanism of high salt ion concentration, the effect of testing conditions
on salt ion diffusion behavior by a Mettler SevenExcellence multiparameter
conductivity instrument and then salt ions in soaked solution are
analyzed. The study samples are selected from lacustrine shale from
the Upper Cretaceous Qingshankou Formation. The testing conditions
include measuring sites, stirring or not, particle size, sample weight,
solution volume, and initial solution concentration. The experiment
has perfect repetition as long as 238 days. The conductivity measured
at the upside is lower than the one measured at the downside before
10 days and becomes similar after 10 days. Stirring before measurement
increases the salt ion diffusion rate obviously before 10 days, which
has less influence on the late period. The smaller the particle size
is, the higher the conductivity is. The ratio between conductivity
and sample weight decreases with sample weight increase. The higher
the liquid volume is, the higher the total salt ion in liquid is at
last. The initial salt ion concentration has less influence on the
salt ion diffusion behavior, which is mainly controlled by its own
physical property. Salt ion diffusion needs a long time to approach
stability, and the conductivity in some samples is still increasing
after 218 days. The main anions in soaked solution are SO4
2–, Cl–, and NO3
–, and the main cations are Na+, Ca2+, Mg2+, K+, Si4+, and Sr2+. Cl– and Sr2+ are mainly from precipitated
salt ions in pores, and other salt ions are partially from precipitated
salt ions in pores. Our study contributes to understanding the influencing
factors for evaluating the salt ion diffusion behavior in the shale
reservoir and clarifying the salt ion component in soaked solution,
which is conducive to the explanation of flowback fluid with a higher
salt ion concentration in clay-rich shale reservoirs. Our research
contributes to the selection of high productive shale oil formation.