The basic question which this thesis seeks to answer is: 'Was the baseflow which flowed continuously in Lockyer Creek prior to 1980 outflow from adjacent alluvial aquifers or was it outflow from basalt aquifers on the Main Range?' This question was not obvious at the start of the project when information from 'official' sources suggested that Lockyer Creek was ephemeral, and there was no baseflow.To answer this question, it was necessary to define baseflow (as outflow from aquifers) and to devise a means of separating it from overland flow, because the existing methods separate 'quick flow' from 'prolonged flow': not overland flow from baseflow. The existence of baseflow presumes the existence of aquifers in the catchment, so geology of the catchment was examined to identify its aquifers.Streamflow records at four sites: three upstream and one downstream, were analysed to establish that baseflow was a significant component (25%) of streamflow over the period 1910-2000, and that average baseflow over this period was close to the estimated long-term safe yield of the Lockyer alluvium. The process of aquifer recharge was analysed and it was concluded that the alluvial aquifers are recharged by infiltration of water mainly through the bed of creeks and saturated flow in the aquifer below the water table, followed by unsaturated flow across a saturated/unsaturated boundary at the wetting front. Saturated flow is driven by the hydraulic gradient on the water table (which was shown in 1949 to slope away from creeks) while unsaturated flow is driven by the matric potential across the wet and dry sides of the front. Unsaturated flow is orders of magnitude slower than saturated flow but takes place over a much greater area than saturated flow. Because it is such a slow process, long duration flows are required to achieve significant aquifer recharge. Chemical analyses of water from basalt aquifers, baseflow and alluvial aquifers confirmed that the 'ionic signature' of the three waters was similar, which would be expected if baseflow was outflow from basalt aquifers, which in turn recharged alluvial aquifers. The ionic signature of water in the adjacent sandstones is quite different from that of these three waters. Ions present in water in the alluvium, including the sodium vii Glossary Adsorbed water: The water held in soil by surface-attractive forces: the attraction between unlike charges, such as the positive charges on hydrogen ions and the negative charges on oxygen ions. Generally, the more surface (the more clay and organic matter) a soil has, the greater is the amount of adsorbed water.Aquifer: A saturated permeable geological unit that can transmit significant quantities of water under ordinary hydraulic gradients (Freeze and Cherry 1979); a geological unit which contains water and transmits it from one point to another in quantities sufficient to permit economic development (Linsley et al. (1982). It is suggested that, for a lithologic unit to be considered to be an aquifer, it should have a hydraulic conductivit...