† Supporting information (SI) availableKeyword: quad-band filter, hybrid photovoltaic-thermal collector, solar absorptance, thermal emittance Hybrid photovoltaic-thermal (PVT) solar collectors are being explored to capture the full spectrum of solar energy. Currently, most beam splitting concepts rely on filters that divert photons below the bandgap and/or photons above the bandgap to another solar thermal collector, and the rest for PV conversion. Here, we demonstrate a different strategy: photons of the solar spectrum in the desirable PV band are reflected, while the rest of the photons in the solar spectrum (i.e., below-the-bandgap and high-energy photons) are absorbed in the beam splitter to raise its temperature. The beam splitter also has low emittance in the mid-infrared, effectively suppressing thermal re-radiation losses. The concept is illustrated with a SiO 2 /TiO x multilayered interference filter deposited on top of a conventional ceramic-metal solar thermal absorber, which has high broadband solar absorptance but low infrared emittance. The resulting quad-band filter with four distinct bands (i.e., high reflectance in the PV band, high absorptance above and below the PV band in the solar spectrum, and high reflectance in the middle-to longwavelength infrared range) offers a new approach for spectral splitting of photons to harvest the full solar spectrum by combining solar PV and solar thermal systems.2