Given a 0-dimensional scheme X in a n-dimensional projective space P n K over an arbitrary field K, we use Liaison theory to characterize the Cayley-Bacharach property of X. Our result extends the result for sets of Krational points given in [7]. In addition, we examine and bound the Hilbert function and regularity index of the Dedekind different of X when X has the Cayley-Bacharach property.Theorem 1.1. Let W be a set of points in P n K which is a complete intersection, let X ⊆ W, let Y = W \ X, and let I W , I X and I Y denote the homogeneous vanishing ideals of W, X and Y in P = K[X 0 , ..., X n ], respectively. Set α Y/W = min{i ∈ N | (I Y /I W ) i = 0 }. Then the following conditions are equivalent.(a) X is a Cayley-Bachrach scheme. (b) A generic element of (I Y ) α Y/W does not vanish at any point of X. (c) We have I W : (I Y ) α Y/W = I X .