The Decomposition of Methyl Oleate Hydroperoxide in Saturated Hydrocarbons and Methyl Esters of Fatty Acid

Effect of polar substances on the decomposition of hydroperoxy oleate on heating

“…stearic acid accelerated the decomposition of methyl hydroperoxy linoleate with formation of a free radical [4]. After SLIWIOK et al [5, 61 even alcoholic groups affect the rate of hydroperoxide decomposition while ester groups of fats and oils have no appreciable effect [7]. The decomposition is influenced by access of oxygen as well.…”

Effect of the Amount of Liquid Phase in Packed Column GC on Air Oxidation Product of Methyl Oleate

“…Methyl hydroperoxyoleate (methyl hydroperoxyoctadecenoate) was prepared by autoxidation of methyl oleate (methyl cis-9-octadecenoate), followed by purification treatments using a solvent extraction with methanol-water (88:12,v/v) from the heptane solution of the oxidation products and subsequent urea adducts purification method 7) . The peroxide value of the intended product was 6100 meq.…”