The decarbonylation of aldehydes by tris(triphenylphosphine)chlororhodium(I)

Baird, Michael C.; Nyman, C. J.; Wilkinson, Geoffrey

doi:10.1039/j19680000348

Cited by 66 publications

(23 citation statements)

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“…Unfortunately, the aldehydes resulting from primary alcohols as donors are known to act as catalyst poisons. Furthermore, they may decarbonylate, forming CO, which may modify the catalysts and consequently change their activity [65,66].…”

Section: Hydrogen Donorsmentioning

confidence: 99%

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Transfer Hydrogenation Including the Meerwein‐Ponndorf‐Verley Reduction

Klomp¹,

Hanefeld²,

Peters³

2006

The Handbook of Homogeneous Hydrogenation

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Section: Hydrogen Donorsmentioning

confidence: 99%

“…They can poison the catalyst or decarbonylate, forming CO, which may coordinate to the metal complex and result in a change in activity (Scheme 20.26) [65,66].…”

Section: Decarbonylationmentioning

confidence: 99%

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Transfer Hydrogenation Including the Meerwein‐Ponndorf‐Verley Reduction

Klomp¹,

Hanefeld²,

Peters³

2006

The Handbook of Homogeneous Hydrogenation

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“…Finally,u ncontrollableh ydrogenation of unsaturated aldehydes often accompanies the hydrogenation of the carbonyl group. [19] Therefore, to develop highly selective protocols, new catalysts operating according to alternative mechanisms may be employed.…”

Section: Catalysismentioning

confidence: 99%

Polymer‐Anchored Bifunctional Pincer Catalysts for Chemoselective Transfer Hydrogenation and Related Reactions

et al. 2019

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A series of polymer‐supported cooperative PC(sp3)P pincer catalysts was synthesized and characterized. Their catalytic activity in the acceptorless dehydrogenative coupling of alcohols and the transfer hydrogenation of aldehydes with formic acid as a hydrogen source was investigated. This comparative study, examining homogeneous and polymer‐tethered species, proved that carefully designing a link between the support and the catalytic moiety, which takes into consideration the mechanism underlying the target transformation, might lead to superior heterogeneous catalysis.

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“…Rhodium-catalyzed hydroformylation has been studied extensively (16)(17)(18)(19)(20)(21)(22)(23)(24)(25)(26)(27)(28)(29). The most active catalyst source is hydridocarbonyltris(triphenylphosphine)rhodium, HRhCO[P(C 6 H 5 ) 3 ] 3 (30).…”

Section: Hydroformylation and Hydrogenationmentioning

confidence: 99%