1971
DOI: 10.3891/acta.chem.scand.25-1655
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The Crystal Structure of Mercury(I) Hexafluorosilicate Dihydrate.

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Cited by 19 publications
(7 citation statements)
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“…The structure is built up of the complex aquo-cation [H20-Hg-Hg-OH2] and nitrate anions. The interatomic distances of Hg-Hg 2.508/~ and Hg-OHz 2.13 A with the bond angle Hg-Hg-OH2 of 167.5"" (Table 2) are in perfect agreement with the values reported for the crystal structure of the analogous mercurous compounds (Johansson, 1966;Dorm, 1971). The interatomic distances and bond angles in the nitrate ion also agree well with the known data (Addison, Logan, Walwork & Garner, 1971).…”
supporting
confidence: 86%
“…The structure is built up of the complex aquo-cation [H20-Hg-Hg-OH2] and nitrate anions. The interatomic distances of Hg-Hg 2.508/~ and Hg-OHz 2.13 A with the bond angle Hg-Hg-OH2 of 167.5"" (Table 2) are in perfect agreement with the values reported for the crystal structure of the analogous mercurous compounds (Johansson, 1966;Dorm, 1971). The interatomic distances and bond angles in the nitrate ion also agree well with the known data (Addison, Logan, Walwork & Garner, 1971).…”
supporting
confidence: 86%
“…Only a few crystal structures of¯uorinated and hydrated compounds containing Hg in different oxidation states are known, namely HgF(OH) (Sta Ê lhandske, 1979), HgF 2 (H 2 O) 2 (Bukvetskii et al, 1976), Hg 2 AlF 5 (H 2 O) 2 (Fourquet et al, 1981), Hg 2 SiF 6 (H 2 O) 2 (Dorm, 1971), Hg 2 (OH) 2 SiF 6 (H 2 O) 2 (Golovastikov, 1984), HgFeF 5 (H 2 O) 2 (Fourquet et al, 1985) and Hg 2 FeF 5 (OH) 2 (H 2 O) (Courant et al, 1985). The present work on Hg 3 AlF 6 O 2 H forms part of a project to prepare such phases under different conditions.…”
Section: Commentmentioning
confidence: 99%
“…Hg-Hg distance is indistinguishable from those in similar compounds (Grdeni6, 1956;Johansson, 1966;Dorm, 1971). Table 2 presents characteristic distances for the structure.…”
Section: Structure Of Dimercury(i) Aluminium(iii) Fluoride Dihydratementioning
confidence: 85%
“…Only very few crystal structures of fluorinated compounds containing Hg I are known: Hg2F2 (Grdeni6 & DjordjeviO, 1956), Hg2SiF6.2H20 (Dorm, 1971). The present work on Hg2AIFs.2H20 forms part of a research programme on inorganic fluorinated compounds containing monovalent mercury.…”
mentioning
confidence: 95%