The crystal structure of catena-poly[(μ₂-2-((3-bromo-2-oxidobenzylidene)amino)acetato-κ⁴ O,N,O′:O′′)-(dimethylformamide-κ¹ O)]zinc(II), C₁₂H₁₃N₂O₄BrZn

Abstract

<jats:title>Abstract</jats:title><jats:p>C<jats:sub>12</jats:sub>H<jats:sub>13</jats:sub>N<jats:sub>2</jats:sub>O<jats:sub>4</jats:sub>BrZn, monoclinic, <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub>/<jats:italic>n</jats:italic> (no. 14), <jats:italic>a</jats:italic> = 12.0182(12) Å, <jats:italic>b</jats:italic> = 6.9735(7) Å, <jats:italic>c</jats:italic> = 16.2510(14) Å, <jats:italic>β</jats:italic> = 93.572(9)°, <jats:italic>V</jats:italic> = 1359.3(2) Å<jats:sup>3</jats:sup>, <jats:italic>Z</jats:italic> = 4, <jats:italic>R</jats:italic><jats:sub>gt</jats:sub>(<jats:italic>F</jats:italic>) = 0.0279, <jats:italic>wR</jats:italic><jats:sub>ref</jats:sub>(<jats:italic>F</jats:italic><jats:sup>2</jats:sup>) = 0.0613, <jats:italic>T</jats:italic> = 293(2) K.</jats:p>

Synthesis, Crystal Structure of Tetra-Nuclear Macrocyclic Zn(II) Complex and Its Application as Catalyst for Oxidation of Benzyl Alcohol

“…The molecular structure of tetranuclear macrocyclic Zn(II) complex (1). 3) Å (Zn-N), respectively, which are comparable to other Zn(II) complexes [31][32][33]. The tetranuclear macrocyclic Zn(II) complex (1) assemble an extended 3D supramolecular network matic rings of ligands (Figure 2).…”