The crystal structure of ?-cyclopentadienylazotoluenenickel

Semion, V. A.; Barinov, I. V.; Ustynyuk, Yu. A.; Struchkov, Yu. T.

doi:10.1007/bf00743856

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1973

1993

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Cited by 10 publications

(1 citation statement)

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“…The fluorinated azobenzene ligand is bound in a chelating fashion similar to that observed for unsubstituted azobenzene in two rhodium complexes20-21 and in a palladium dimer22 and for azotoluene in a cyclopentadienylnickel complex. 23 The free CeFs group is twisted by an angle of 64.6°from the plane of the five-membered chelate ring. The magnitude of this twist is greater than the range of values of 14-54°p reviously observed for metalated azobenzene and azotoluene ligands.…”

Section: P-ru-clmentioning

confidence: 99%

Crystal and molecular structure of a ruthenium complex containing a metalated perfluoroazobenzene ligand and a novel 2-(.eta.-cyclopentadienyl)phenyl group

Moreland¹,

Doedens²

1976

Inorg. Chem.

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Section: P-ru-clmentioning

confidence: 99%

Crystal and molecular structure of a ruthenium complex containing a metalated perfluoroazobenzene ligand and a novel 2-(.eta.-cyclopentadienyl)phenyl group

Moreland¹,

Doedens²

1976

Inorg. Chem.

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Die Molekül‐ und Kristallstruktur von 3,3‐Bis(methoxycarbonyI)4‐phenyl‐1‐pyrazolin‐N‐(tetracarbonyleisen)

Krüger

1973

Chem. Ber.

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Die Rontgenstrukturanalyse dcr Titclverbindung (Zelldaten: u : : 10.113 (2), h 27.548 (7), c 6.938 (2) A, /3 = 99.53 (2)', P2l/c, Z = 4) bewcist die cr-Komplexbildung zwischen einem 1 -Pyrazolin-Derivat uitd eineni Ubergangsmetall. Dcr Ligand ist iiberraschenderweise in apikaler Position an einen trigondl-bipyramidalen Fe(C0)4-Resl gebunden. Die Ceometrie des Liganden andert sich durch die Komplexierung nicht wesentlich. The Molecular und Crystal Structure of 3,3-Bis(methoxycarbonyl)-4-phenyl-l-p~~razo1ine-~-(te~acarbony1iron)The single crystal x-ray analysis of the title compound (cell data: u ~ 10.113 (2), b = 27.548(7). c = 6.938 (2) A, p = 99.53 (2)", P21/c, Z : 4) shows the I-pyrazoline derivative to be linked through a a-bond to the apical position of a Fe(C0)4 residue. The geometry or the ligand is not altered upon complexation.

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The crystal structures of the complexes [M(C6H4NNPh)(η5-C5H5)], M = Ni, Pd and Pt

Anderson

Cross

Muir

et al. 1989

Journal of Organometallic Chemistry

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The crystal structure of ?-cyclopentadienylazotoluenenickel

Cited by 10 publications

References 8 publications

Crystal and molecular structure of a ruthenium complex containing a metalated perfluoroazobenzene ligand and a novel 2-(.eta.-cyclopentadienyl)phenyl group

Crystal and molecular structure of a ruthenium complex containing a metalated perfluoroazobenzene ligand and a novel 2-(.eta.-cyclopentadienyl)phenyl group

Die Molekül‐ und Kristallstruktur von 3,3‐Bis(methoxycarbonyI)4‐phenyl‐1‐pyrazolin‐N‐(tetracarbonyleisen)

The crystal structures of the complexes [M(C6H4NNPh)(η5-C5H5)], M = Ni, Pd and Pt

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