The crystal structure of bis(methyl thiohydroxamate)nickel(II)

Sato, Tomohiro; Nagata, Koji; Tsukuda, Y.; Shiro, Motoo; Koyama, H.

doi:10.1039/c19670000215

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Structure Determination1

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1968

1999

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“…A rhodium complex (267) containing a thiocarbonyl ligand has been reported, the thiocarbonyl coordinating via the carbon atom as in other metal carbonyls. The structure determinations of cis-and transbis-(methylthiohydroxamate)nickel(II) (441,442) are believed to be the first examples of thiohydroxamate ligands to be studied by x-ray methods. Also the structure of [CsHjMoOhSo (461) is the first instance in which two sulfur atoms bridge two metal atoms, and the structure of [SCo3(CO)7]2S2 (462) is the first instance in which two sulfur atoms bridge four metal atoms.…”

Section: Structure Determinationmentioning

confidence: 99%