“…A rhodium complex (267) containing a thiocarbonyl ligand has been reported, the thiocarbonyl coordinating via the carbon atom as in other metal carbonyls. The structure determinations of cis-and transbis-(methylthiohydroxamate)nickel(II) (441,442) are believed to be the first examples of thiohydroxamate ligands to be studied by x-ray methods. Also the structure of [CsHjMoOhSo (461) is the first instance in which two sulfur atoms bridge two metal atoms, and the structure of [SCo3(CO)7]2S2 (462) is the first instance in which two sulfur atoms bridge four metal atoms.…”