We present results of an optical spectroscopic survey using SALT and NOT to build a WISE midinfrared color based, dust-unbiased sample of powerful radio-bright (>200 mJy at 1.4 GHz) AGN for the MeerKAT Absorption Line Survey (MALS). Our sample has 250 AGN (median z = 1.8) showing emission lines, 26 with no emission lines, and 27 without optical counterparts. M1312-2026, the highest redshift object (z = 5.068) in our sample, is the most radio-loud (R=1.4 × 10 4 ) AGN known at z > 5. Overall, our sample is fainter (∆i=0.6 mag) and redder (∆(g − i)=0.2 mag) than radio-selected quasars, and representative of fainter quasar population detected in optical surveys. About 20% of the sources are narrow line AGN (NLAGN) -65% of these, at z < 0.5 are galaxies without strong nuclear emission, and 10% at z > 1.9, have emission line ratios similar to radio galaxies. The farthest NLAGN in our sample is M1513−2524 (z em = 3.132), and the largest (size∼330 kpc) is M0909−3133 (z em = 0.884). We discuss in detail 110 AGN at 1.9 < z < 3.5. Despite representing the radio loudest quasars (median R=3685), their Eddington ratios are similar to the SDSS quasars having lower R. We detect 4 C iv BALQSOs, all among AGN with least R, and highest black hole masses and Eddington ratios. The BAL detection rate (4 +3 −2 %) is consistent with that seen in extremely powerful (L 1.4GHz > 10 25 W Hz −1 ) quasars. Using optical light-curves, radio polarization and γ-ray detections, we identify 7 high-probability BL Lacs. We also summarize the full MALS footprint to search for H i 21-cm and OH 18-cm lines at z < 2.