“…In a previous study, we presented a simple model for the formation of the protective layer. 31 The fast initial corrosion of CO Fe-5Cr-5Si transforms into the exceptionally slow corrosion rate at longer times. The formation of the outer FeS layer slows down the inward diffusion rate of sulfur.…”
The corrosion behavior of two cast Fe-xCr-5Si (x = 0, 5 at.%) alloys has been studied at 800°C in H2-CO2-H2S mixture. The addition of 5 at.% Cr improved the corrosion resistance of the Fe-5Si alloy by forming a protective scale of mixed Cr2O3 and SiO2 at the bottom of a non-uniform scale. The corrosion resistance of the cast Fe-5Cr-5Si alloy was further improved by a magnetron-sputtered film of identical composition that promoted the formation of a protective scale of a Cr2O3-SiO2 mixture at the coating/alloy interface. The mechanisms of forming the protective scales are examined and analyzed.
“…In a previous study, we presented a simple model for the formation of the protective layer. 31 The fast initial corrosion of CO Fe-5Cr-5Si transforms into the exceptionally slow corrosion rate at longer times. The formation of the outer FeS layer slows down the inward diffusion rate of sulfur.…”
The corrosion behavior of two cast Fe-xCr-5Si (x = 0, 5 at.%) alloys has been studied at 800°C in H2-CO2-H2S mixture. The addition of 5 at.% Cr improved the corrosion resistance of the Fe-5Si alloy by forming a protective scale of mixed Cr2O3 and SiO2 at the bottom of a non-uniform scale. The corrosion resistance of the cast Fe-5Cr-5Si alloy was further improved by a magnetron-sputtered film of identical composition that promoted the formation of a protective scale of a Cr2O3-SiO2 mixture at the coating/alloy interface. The mechanisms of forming the protective scales are examined and analyzed.
“…When the delayed brittle fracture of metal is caused by the combined action of corrosion and tensile stress in sulfide solution, and the the stress is much less than the yield strength, which is called SSC. It is difficult to monitor and prevent, so hydrogen sulfide corrosion has become a technical problem in the material field worldwide [7][8]. In order to improve the HIC and SSC resistance of low temperature steel pipes, researchers first use the regulation of V, Ti and other microalloy elements to reduce the impact of inclusions, and then use appropriate smelting, rolling and heat treatment processes to optimize the microstructure to refine grains, improve the purity of steel, reduce S and P content, control the number and morphology of non-metallic inclusions [9][10][11], reduce the impact of inclusions, supplemented by appropriate smelting, rolling and heat treatment processes, Finally, the steel pipe with corrosion resistance and low temperature impact performance meeting the standards and operating requirements is obtained.…”
The seamless line pipe, which has fine low temperature impact properties for Low-temperature Service and good H2S corrosion resistance, was investigated through chemical composition designing, optimizing smelting-rolling processes, and heat treatment processes following ASTM A333 standard. The influence of normalizing on the impact property and corrosion resistance was studied by optical microscope, scanning electron microscope, transmission electron microscope, mechanical test and corrosion test. It is demonstrated that the low temperature mechanical properties and anti-H2S corrosion properties of hot-rolled trial-pipe and normalized trial-pipe meet ASTM A333 standard. The microstructure of hot-rolled trial-pipe is pearlite and ferrite, and the grain distribution is uniform and grain size is fine. The dominated precipitates phase are TiN particles in hot-rolled trial-pipe. Ductile to brittle transition temperature is determined at -60 °C. The grain refinement is achieved after normalized and the main precipitates are TiN particles together with a few VN particles. Ductile tobrittle transition temperature was further lowered, at - 80 °C. The corrosion behavior of the material was examined by hydrogen induced cracking (HIC) corrosion test, sulfide stress corrosion (SSC) test and polarization test at various polarization scanning rates. It is observed that the anti-HIC corrosion performance and SSC corrosion resistance are similar for both hot-rolled and normalized pipes, but the performance of electrochemical corrosion of normalized pipe is better than hot-rolled pipe, which indicates that the normalized pipe is more suitable for demanding corrosive environments.
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