The copper(I) iodide accelerated synthesis of mono- and bisbenzyl substituted 1- and 2-aminoanthraquinones

Effects of green tea on ACE gene expression in rat liver in CCl4-induced cirrhosis

“…Therefore, the quaternary ammonium salt can be avoided and multiple benzylation can be controlled. 101 Moreover, at higher applied temperature more bisbenzyl substituted 2-aminoanthraquinones 58 are produced. Thus, during the synthesis of monobenzyl substituted 2-AAQ's 59, the temperature must be maintained below 100 • C. Meanwhile, the benzyl bromide 57 should be added dropwise and 2-AAQ must be in excess.…”

“…Thus, during the synthesis of monobenzyl substituted 2-AAQ's 59, the temperature must be maintained below 100 • C. Meanwhile, the benzyl bromide 57 should be added dropwise and 2-AAQ must be in excess. 101 Reaction with 4,5-dichloro-l,2,3-dithiazolium chloride 2-AAQ was condensed with 4,5-dichloro-l,2,3-dithiazolium chloride (60) in dichloromethane at room temperature, followed by addition of pyridine, to give the desired 2-(4-chloro-[1,2,3]dithiazol-5-ylideneimino)anthraquinone (61) in good yields. 102 Microwave irradiation (150 W) of imino-l,2,3-dithiazole derivative 61 at 150 • C in the presence of a small amount of graphite (10% by weight) surprisingly afforded the angular 2-cyanobenzothiazole 62.…”

Synthesis and characterisation of azobenzene-bridged cationic–cationic and neutral–cationic electrochromic materials

“…Consequently, ECMs have attracted extensive research attention from researchers since Platt [14] reported the electrochromic phenomenon in dyes. ECMs include inorganic materials, such as metal oxides [15][16][17][18], and organic materials, such as phenothiazine [19][20][21][22][23][24], anthraquinone [25][26][27][28][29][30][31][32], viologen [33][34][35][36], thiophene [37][38][39][40], polythiophene [41][42][43][44][45][46][47], polyaniline [48][49][50], polypyrrole [51][52][53][54], and polyimide [55]. Compared with inorganic ECMs, organic ECMs exhibit the unique advantages of high optical contrast, fast switching speed, flexible device fabrication, and a multitude of achievable colors via chemical structure variation.…”

Laws of Dissolution of Copper Electrodes Polarized by the Alternating Current in Solution of Potassium Iodide

“…Copper (I) iodide, in conjunction with 1.10-phenanthroline as ligand, accelerates the reaction rate and enhances reaction yields by ∼30% [10].…”