The Coordination Chemistry of Phosphinines: Their Polydentate and Macrocyclic Derivatives

Study of metal nanoparticles stabilised by mixed ligand shell: a striking blue shift of the surface-plasmon band evidencing the formation of Janus nanoparticles

“…23 (3,5)-Diphenylphosphinine 1 has many structural features that differ from the alkylthiols used here (2 and 3), including aromaticity, the ability to p-stack, and the fact that it is a strong electron acceptor to the gold core. 24,25 Total exchange of phosphinine by thiols has been shown to be easy. 26 Thiols with very different functionalities are readily available, enabling one to study the influence of the thiols physicochemical properties on the desired phase segregation.…”

P,N-Chelate Complexes of Pd(II) and Pt(II) Based on a Phosphaalkene Motif: A Catalyst for the Overman−Claisen Rearrangement

“…Significant contributions to this area have stemmed from the development of cyclic divalent phosphorus systems. As examples, phosphinines ( A , and B , ), phosphaferrocenes ( C , ), and α-iminophospholyl ( D ) compounds have all been employed successfully as ligands for metals, and complexes of A , B , and C have been successfully employed in catalysis. Examples that have an acyclic phosphaalkene motif are more limited in scope.…”

[Re(CO)3Cl(C5H4ClP)2] and [Re(CO)2Cl(C5H4ClP)3]: synthesis and characterization of two novel rhenium(i) phosphinine complexes

“…21,22 Although potential implementation of phosphinine transition metal complexes in homogeneous catalysis has been discussed in the literature, to the best of our knowledge, electron rich rhenium(I) complexes featuring h 1 -coordinated phosphinines have not been reported in more detail, despite the scattered mentioning of such compounds. 4,6,23 The facile synthesis and characterization of two novel rhenium(I) complexes cis-[Re(CO) 3 Cl(h 1 -C 5 H 4 ClP) 2 ] (1) and mer-[Re(CO) 2 Cl(h 1 -C 5 H 4 ClP) 3 ] (2) are reported in this work.…”