The Coordination Chemistry of Metal Complexes Derived from Binucleating Ligands

Synthesis, properties, and crystal structures of new mono- and homo-binuclear uranyl(VI) complexes with compartmental Schiff bases

“…Basically, dinucleating ligands for d-transitionmetal ions have been synthesized, and many complexes have been prepared and studied by different techniques. 19, 20 Of course, the same or very similar ligands have successfully been applied to the preparation of f-transition-metal complexes.' 7 7 1 8.2 '…”

Surprising Magnetic Behavior of Cobalt(II) Ion in Recently Prepared Macrocycle Complexes. Distortion versus Intermolecular Antiferromagnetic Exchange Interactions

“…Metal complexes with macrocycle ligands have gained an accelerated research interest in recent years because of their unique coordination chemistry [1][2][3][4][5][6][7][8][9][10][11][12]. Such compounds usually behave as model ligands for metal enzymes, as metal ion selective ligands and as metal chelating agents for medical purposes.…”

Organized assemblies of lead(ii) complexes of a tetraiminodiphenol macrocyclic ligand: manifestation of weak metal–anion interactions and the directional influence of anions

“…Over the past three decades extensive studies have been made on the chemistry of phenolate-bridged metal complexes derived from Schiff base-type dinucleating macrocyclic ligands I. [1][2][3][4][5][6] The symmetric ligand II has been of particular interest because it provides an ideal platform for the investigation of cooperative interactions between two metal centres (the same or different) under identical stereochemical environments. The focus of interest in complexes of this sort has been the probing of magneto-structural relations, 7-14 redox activities 3,6,15-21 and selective activation of substrates.…”