The construction, operation and performance of a reactive gas generator; with specific application to HCHO, CH₃CHO, CH₂CHCHO, SO₂, HCN and HCl production

Walker, James A.; Tsang, Wing M.

doi:10.6028/nbs.ir.76-1000

Cited by 3 publications

(2 citation statements)

References 1 publication

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“…are not important. Hydroxyl radicals produced in eq 3 can react with ethylene, ozone, formaldehyde, or carbon monoxide: OH + C2H4 -C2H4OH (8) OH + O3 -H02 + 02 (9) OH + CH20 -H20 + HCO (10)…”

Section: Discussionmentioning

confidence: 99%

Stopped-flow studies of the mechanisms of ozone-alkene reactions in the gas phase. Ethylene

Herron¹,

Huie²

1977

J. Am. Chem. Soc.

115

110

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Section: Discussionmentioning

confidence: 99%

Stopped-flow studies of the mechanisms of ozone-alkene reactions in the gas phase. Ethylene

Herron¹,

Huie²

1977

J. Am. Chem. Soc.

115

110

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“…[1][2][3][4][5] It is often used as a starting point in the synthesis of dyes and biologically active compounds. [6][7][8][9][10] Isatin derivatives ( Figure 1) also find applications in the field of solar energy, [11][12][13] organic memory devices 14 and organic field-effect transistors 15,16 Nevertheless there are only a few works that deal with investigations of the addition reactions of isatin derivatives with multiple carbon-carbon bonds. Thus, an addition of isatin and some of its derivatives to the C=N bond of isocyanates and C=C bond of diphenylketene to form 1-carbamoylisatins and 1-diphenylacetylisatin respectively, have been described.…”

Section: Introductionmentioning

confidence: 99%

A catalyst-free and easy nucleophilic addition of certain isatins to sterically hindered 2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dienone

Богданов¹,

Бухаров²,

Oludina³

et al. 2013

Arkivoc

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Addition of substituted isatins to 2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dienone, generated in situ from 3,5-di-tert-butyl-4-hydroxybenzyl acetate, to form 1-substituted hydroxybenzylisatins, is reported. On the basis of these isatins novel isatin-3-thiosemicarbazones as well as isoindigo derivatives bearing a 2,6-di-tert-butylphenol moiety were obtained. The structures of all novel compounds are confirmed by IR, 1 H NMR and 13 C NMR.

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Thermal decomposition of hexamethylethane in a flow system

Walker

Tsang

1979

Int J of Chemical Kinetics

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Hexamethylethane has been decomposed in a flow system in the temperature range of 700-900 K. The mechanism involves carbon-carbon bond cleavage a t the most highly substituted position and rapid formation of isobutene from the t-butyl radical. The rate expression is k((tC4H9)2 -2tC4Hy) = l O I 7 exp(-36,000/T) sec-l and is completely consistent with deductions from radical buffer, shock-tube, and direct recombination studies. Of special importance is experimental evidence for large decreases of the A factor with increasing temperature and a high heat of formation for the t-butyl radical, AH~(tC4Hy)3m = 52.7 f 6 kJ.

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The construction, operation and performance of a reactive gas generator; with specific application to HCHO, CH₃CHO, CH₂CHCHO, SO₂, HCN and HCl production

Abstract: HCl production are discussed.

Cited by 3 publications

References 1 publication

Stopped-flow studies of the mechanisms of ozone-alkene reactions in the gas phase. Ethylene

Stopped-flow studies of the mechanisms of ozone-alkene reactions in the gas phase. Ethylene

A catalyst-free and easy nucleophilic addition of certain isatins to sterically hindered 2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dienone

Thermal decomposition of hexamethylethane in a flow system

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