Abstract:Recent studies on the cis-and trans-1,2-dibenzoylethylenes and benzalacetophenones (2-4) are of interest in connection with the possibility of assignment of configurations to the alkoxy, aroxy, hydroxy, amino, and alkylaminodibenzoylethylenes (I, II, VIII, IX), and have led to the further work described in this paper.Methoxydibenzoylethylene (I) (5-9), known in only one form, has been regarded (probably correctly) as thermodynamically the more stable of the two possible stereoisomers, and because of this it wa… Show more
“…The overall yields were calculated using the attenuation coefficient of DBE ( ε = 18.1 × 10 3 M −1 cm −1 ). 90,91 Additional experiments confirmed the stability of the photosensitizers and DPF under the chosen conditions (ESI† Fig. S11.14–S16), and the necessity for light and the PSs themselves to achieve conversion (ESI† Fig.…”
Motivated by the need to design efficent photocatatalysts based on eart-abundant metals and to elucidate essential structure-property relationships this study deals with heteroleptic copper(I) complexes. A systematic series of four...
“…The overall yields were calculated using the attenuation coefficient of DBE ( ε = 18.1 × 10 3 M −1 cm −1 ). 90,91 Additional experiments confirmed the stability of the photosensitizers and DPF under the chosen conditions (ESI† Fig. S11.14–S16), and the necessity for light and the PSs themselves to achieve conversion (ESI† Fig.…”
Motivated by the need to design efficent photocatatalysts based on eart-abundant metals and to elucidate essential structure-property relationships this study deals with heteroleptic copper(I) complexes. A systematic series of four...
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