The Conductance of Aqueous Solutions of Sodium Chloride, Hydrochloric Acid and Their Mixtures.

Abstract

BOBTON, Match, 1911. [CONTRIBUTIONS FROM THE RESEARCH LABORATORY OF PHYSICAL CHEMISTRY OF THE MASSACHUSETTS INSTITUTE OF TECHNOLOGY, NO. 68.1 THE CONDUCTANCE AND IONIZATION OF CERTAIN SALTS AT 18" AND 25". BY FRANKLIN 4. HURT.

Hittorf Transference Numbers of Solutions of Potassium, Sodium, and Lithium Chlorides in Water and in One-tenth Molar Hydrochloric Acid

“…The reaction accompanying the retardation of the H+ ions will result in an acceleration of the R+ ions, whilst the motion of the Clions will be very slightly decreased. The measurements of the same authors (Hittorf transference numbers in HC1 + KC1) are in qualitative agreement with the extended theory, as also are those of Longsworth (10) (transference measurements by moving boundary method in HC1 + KC1), of Bray and Hunt (5) (conductance measurements in HC1 + NaCl), and of Miss Taylor (16) (Hittorf transference numbers in HC1 + NaCl).…”

Atomic Biology, Electrostatics, and Ionic Channels

“…12 Non-ideal behavior is even more apparent in the nonequilibrium properties of mixed electrolyte solutions, e.g., in their conductance. "It has long been known (Bray and Hunt, 1911), that the conductances of even very dilute solutions of mixed electrolytes are not additive, so that Kohlrausch's law of independent ionic mobilities is not valid for mixtures." (Kortum,  1965, p. 211).…”

Mixtures of Colloidal Electrolytes with Uni-univalent Salts.

“…For comparison with the observed data for mixtures, it is customary to make use of various simple additive rules (2,8,10,11). We have used three.…”