The Compressions and Specific Volumes of Aqueous Solutions of Resorcinol and Methanol at 25° and the Behavior of Water in these Solutions

Thermodynamic properties of {xCH3OH +(1−x)H2O} withx= (1.0000 and 0.4993) in the temperature range from 320K to 420K at pressures up to 200MPa

“…Here, for pure CH 3 OH the densities of the present measurements given in table 2 were used, whereas the densities for H 2 •, present work with an error bar at x = 0.4993; , Kubota and Tsuda (5) at x = 0.5; , Götze and Schneider (6) at x = 0.5; •, Easteal and Woolf (7) at x = 0.5; +, Xiao et al (8) at x = 0.49641; ×, McGlashan and Williamson (32) at x = 0.49446; , Chen et al (41) …”

“…Measurements of the volumetric properties of aqueous methanol mixtures as a function of temperature and pressure have been reported in several papers. (2)(3)(4)(5)(6)(7)(8) To understand the properties of aqueous methanol mixtures and to provide accurate data for the design of processes and plants, we carried out thermodynamic measurements on the properties of methanol and its aqueous mixtures in the compressed phase. The present paper …”

Correlation and prediction of thermodynamic properties of nonelectrolytes at infinite dilution in water over very wide temperature and pressure ranges (2000K and 10GPa)

“…13b) fall on a single universal curve. The sources of V 1 2 are numerous (Moesveld, 1923;Howell, 1932;Gibson, 1935;Alexander, 1959;Fig. 11.…”

Excess molar volumes VmE, isothermal compressibilities k, and thermal expansivities α of {(1−x)H2O+xCH3OH} at T=(298.15 to 523.15) K and pressures up to 60 MPa

“…The previous experimental works [3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18] on the excess molar volumes V E m , isothermal compressibilities k, and thermal expansivities a are tabulated in table 1. Many papers include a small range of state parameters.…”