Phase evolution, microstructure, and microwave dielectric properties of Li 2 O and Al 2 O 3 doped Zn 1.9 Si 1.05 O 4 , i.e., Zn 1.9-2x Li x Al x-Si 1.05 O 4 , ceramics (x = 0.02~0.10) were investigated. The ceramics were densified by SiO 2-rich liquid phase composed of the Li-Al-Si-O system, indicating that doped Li and Al contributed to the formation of the liquid. As the secondary phase, β-spodumene solid solution with the composition of LiAlSi 3 O 8 was precipitated from the liquid during the cooling process. The dense ceramics were obtained for the specimens of x 0.06 showing the rapid densification above 1000 o C, implying that a certain amount of liquid is necessary to densify. The specimen of x = 0.06 sintered at 1050 o C exhibited good microwave dielectric properties; the dielectric constant and the quality factor (Q × f 0) were 6.4 and 11,213 GHz, respectively.