The moduli space M d of degree d ≥ 2 rational maps can naturally be endowed with a measure µ bif detecting maximal bifurcations, called the bifurcation measure. We prove that the support of the bifurcation measure µ bif has positive Lebesgue measure. To do so, we establish a general sufficient condition for the conjugacy class of a rational map to belong to the support of µ bif and we exhibit a large set of Collet-Eckmann rational maps which satisfy that condition. As a consequence, we get a set of Collet-Eckmann rational maps of positive Lebesgue measure which are approximated by hyperbolic rational maps.