1973
DOI: 10.1007/bf00713250
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The CO2-water system. I. Study of the slower hydration-dehydration step

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Cited by 15 publications
(9 citation statements)
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“…The ion pairing reaction [5] is shown for the K+ and C032-ions, as this is the most likely equilibrium to be of consequence in the studies reported here. Equilibria involving divalent cations are of more importance in natural waters (3), and the HC03-ion would also be involved in such equilibria (10, 11).…”
Section: The Square Brackets Indicate Concentration In Mol L-' (M)mentioning
confidence: 53%
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“…The ion pairing reaction [5] is shown for the K+ and C032-ions, as this is the most likely equilibrium to be of consequence in the studies reported here. Equilibria involving divalent cations are of more importance in natural waters (3), and the HC03-ion would also be involved in such equilibria (10, 11).…”
Section: The Square Brackets Indicate Concentration In Mol L-' (M)mentioning
confidence: 53%
“…Some 13C nmr, however, has been used to study the enzyme catalysis of reactions [2] assumed speciation reactions [l] to [5]. The discussion is supported by further Raman data and speciation calculations.…”
Section: The Square Brackets Indicate Concentration In Mol L-' (M)mentioning
confidence: 98%
See 1 more Smart Citation
“…It has been suggested that in some cases the apparent discrepancies may simply reflect an inappropriate estimate of used in the calculation of ^h2co3 (Knoche 1980). The most recent paper on carbonic acid dehydration (van Eldik & Palmer 1982) proposes that the value of 19 s_1 for ^h2co3 determined by Patel et al (1973) should be taken as the most reliable. The rather low value of Gibbons & Edsall has been explained by the fact that phosphate (used as a buffer in their solutions) was considered to have a catalytic effect on the rate of dehydration, and the rate constant was therefore corrected.…”
Section: T Heorymentioning
confidence: 99%
“…The chemical reaction of CO 2 with water to form carbonic acid is clearly the central feature of these carbonate equilibria, and has been addressed by many experiments [5,16,[18][19][20][21][22][23][24][25][26] and calculations [17,[27][28][29][30][31][32][33][34][35][36] with conflicting results. Details of the neutral CO 2 solvation by bulk water prepare the reaction pathway, and are thus a determining factor in this chemistry.…”
Section: Introductionmentioning
confidence: 99%