2006
DOI: 10.1016/j.gca.2006.06.1551
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The citric acid–MnIII,IVO2(birnessite) reaction. Electron transfer, complex formation, and autocatalytic feedback

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Cited by 77 publications
(72 citation statements)
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“…The XRD analysis yielded dspacing patterns located at 7.23, 3.66, 2.57 and 1.69 Å. These patterns are consistent with the literature (Wang and Stone, 2006a (Fig. 3).…”
Section: Manganese Dioxide Preparation and Characterizationsupporting
confidence: 90%
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“…The XRD analysis yielded dspacing patterns located at 7.23, 3.66, 2.57 and 1.69 Å. These patterns are consistent with the literature (Wang and Stone, 2006a (Fig. 3).…”
Section: Manganese Dioxide Preparation and Characterizationsupporting
confidence: 90%
“…Perhaps most interesting was that the initial Mn(II) dissolution from the Cu-Citrate 1:0.5 and 1:1 (oxic) solutions followed the ionic Cu(II) curve, in contrast to the s-shaped induction curves of Mn(II) dissolution mediated by citrate found in this study and in Wang and Stone, 2006a. This similarity suggests that Cu-Citrate1:1 (oxic) may form initial ternary surface complexes through the octahedral coordination sphere of the citrate coordinated Cu instead of through the citrate ligand.…”
Section: àcontrasting
confidence: 67%
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“…Here the trisodium citrate was oxidized by I 3 À to produce disodium 1,3-acetonedicarboxylate (C 5 H 4 Na 2 O 5 ). 8 In addition, Au 0 produced by reduction of Au III ions by citrate was reoxidized by I 3 À . In other words, excess I 3 À could prevent Au III ions from being reduced by trisodium citrate.…”
mentioning
confidence: 99%