1939
DOI: 10.1002/recl.19390580808
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The chlorination of pyridine: Investigations on pyridine and quinoline derivatives 41st. Communication

Abstract: On chlorinating pyridine in the gas phase at 270° a good yield of 2‐chloropyridine is obtained together with a small quantity of 2:6‐dicloropyridine. At 400° the main product is 2:6‐dichloropyridine. It is shown that among the products produced in the chlorination at 270°, a small amount of a pyridylpyridinium compound must be present, for 2‐aminopyridine is obtained on hydrolysis of the reation product. Chlorination in the gas phase takes place very slowly at about 200° at this temperature 3:5‐dichloropyridin… Show more

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Cited by 38 publications
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