“…Smoke-borne compounds that are considered responsible for smoke taint in grapes or wines are thought to originate primarily from pyrolysis of the lignin component of vegetation fuels (Hayasaka, Baldock, Parker et al, 2010;Singh et al, in press) analogously to that which occurs in smoke used for curing/flavouring of food (Gilbert & Knowles, 1975;Tóth & Potthast, 1984;Wittkowski, Ruther, Drinda, & Rafiei-Taghanaki, 1992). Lignin is derived mainly from polymerisation of three monolignol precursors: p-coumaryl alcohol, coniferyl alcohol and sinapyl alcohol (Fahmi, Bridgwater, Thain, & Donnison, 2007;Pettersen, 1984;Weng & Chapple, 2010), which respectively constitute the p-hydroxyphenyl, guaiacyl and syringyl units of lignin.…”