The Chemistry of Aliphatic Nitrosulfonates. IV. Coupling with Diazonium Salts

Gold, Marvin; Levine, Harold H.

doi:10.1021/jo50004a002

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1953

2011

Publication Types

Select...

Book3

Other1

Article1

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 5 publications

References 2 publications

(3 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

The Coupling of Diazonium Salts with Aliphatic Carbon Atoms

Parmerter

2011

Organic Reactions

View full text Add to dashboard Cite

A diazonium salt will couple with an aliphatic compound containing an activated carbon‐hydrogen bond. This discussion is limited to those reactions in which both the nitrogen atoms of the diazonium salts are retained in the resulting molecule. The discussion is further limited by the exclusion of coupling reactions, which occur with the elimination of a group from an activated methinyl compound, the Japp‐Klingemann reaction. These reactions are discussed in Chapter 2. Much of the early work with coupling was prompted by the desire to determine whether the products were of the azo or hydrazonestructure. It is difficult to establish the structures in such cases where the tautomeric forms are possible. It is generally considered that the hydrazone is the stable form.

show abstract