The Chemical Action of Gaseous Ions Produced by Alpha Particles Vii. Unsaturated Carbon Compounds

Lind, S. C.; Bardwell, D. C.; Perry, John

doi:10.1021/ja01417a017

Cited by 67 publications

(18 citation statements)

References 2 publications

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“…A significant aspect of the chemistry of the above species is their tendency to polymerize, especially under the influence of ionizing radiation. For example, LlND, BARDWELL, and PERRY [18] investigated the radiation induced polymerization of both cyanogen and hydrogen cyanide and observed the formation of black or reddishbrown polymeric solids with empirical formulae (CN 0 95 )" and (H 0 97 CN 0 97 )", respectively. Unfortunately the structures of these materials were not determined.…”

Section: Discussionmentioning

confidence: 99%

The Characterization of Carbon-14 Rich Deposits Formed in the Nitrogen Gas Annulus Systems of 500 MWe CANDU Reactors

Greening

1989

Radiochimica Acta

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Section: Discussionmentioning

confidence: 99%

The Characterization of Carbon-14 Rich Deposits Formed in the Nitrogen Gas Annulus Systems of 500 MWe CANDU Reactors

Greening

1989

Radiochimica Acta

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“…Quantitative analysis of the energy deposition by the ionizing radiations is crucial for sustainability of lives and materials, however the dosimetry of cosmic rays with a variety of particles and a broad energy spectrum have been challenging to date. Ionizing radiation met polymeric materials in the beginning of 20th century [50,51] as a powerful tool of functionalization by chemical reactions induced via reactive intermediates such as ions, ion radicals, and neutral radials. The reactive intermediates, distributed homogeneously in the bulk polymeric materials, promote crosslinking, main chain scission, and subsequent graft polymerization reactions, which often dramatically improve the physical and mechanical properties of the polymeric materials [52].…”

Section: Single Particle Nanofabrication Technique (Spnt) As a Versatmentioning

confidence: 99%

Interactions of Single Particle with Organic Matters: A Facile Bottom-Up Approach to Low Dimensional Nanostructures

Sakaguchi¹,

Kamiya²,

Sakurai³

et al. 2020

QuBS

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A particle induces a pack of chemical reactions in nanospace: chemical reactions confined into extremely small space provide an ultimate technique for the nanofabrication of organic matter with a variety of functions. Since the discovery of particle accelerators, an extremely high energy density can be deposited, even by a single isolated particle with MeV-ordered kinetic energy. However, this was considered to cause severe damages to organic molecules due to its relatively small bond energies, and lack of ability to control the reactions precisely to form the structures while retaining physico-chemical molecular functionalities. Practically, the severely damaged area along a particle trajectory: a core of a particle track has been simply visualized for the detection/dosimetry of an incident particle to the matters, or been removed to lead nanopores and functionalized by refilling/grafting of fresh organic/inorganic materials. The use of intra-track reactions in the so-called “penumbra” or “halo” area of functional organic materials has been realized and provided us with novel and facile protocols to provide low dimensional nano-materials with perfect size controllability in the 21st century. These protocols are now referred to as single particle nanofabrication technique (SPNT) and/or single particle triggered linear polymerization technique (STLiP), paving the way towards a new approach for nanomaterials with desired functionalities from original molecules. Herein, we report on the extremely wide applicability of SPNT/STLiP protocols for the future development of materials for opto-electronic, catalytic, and biological applications among others.

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“…Hydrocarbons irradiated with a particles are dehydrogenated, whereas in the presence of oxygen, carbon dioxide and water is produced, and the usual dehydrogenation is reduced or suppressed (Lind, Bardwell and Perry, 1926). Hydrocarbons irradiated with a particles are dehydrogenated, whereas in the presence of oxygen, carbon dioxide and water is produced, and the usual dehydrogenation is reduced or suppressed (Lind, Bardwell and Perry, 1926).…”

Section: Effect Of Oxygen and Of Hal Idesmentioning

confidence: 99%

Radiation-Induced Changes in Organic Molecules

Charlesby

1960

Atomic Radiation and Polymers

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The Chemical Action of Gaseous Ions Produced by Alpha Particles Vii. Unsaturated Carbon Compounds

Abstract: A systematic study is herewith presented of the physical and chemical properties of selenium monochloride.Its properties in general are those of a typical acid chloride and a strong chlorinating agent.

Cited by 67 publications

References 2 publications

The Characterization of Carbon-14 Rich Deposits Formed in the Nitrogen Gas Annulus Systems of 500 MWe CANDU Reactors

The Characterization of Carbon-14 Rich Deposits Formed in the Nitrogen Gas Annulus Systems of 500 MWe CANDU Reactors

Interactions of Single Particle with Organic Matters: A Facile Bottom-Up Approach to Low Dimensional Nanostructures

Radiation-Induced Changes in Organic Molecules

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