1986
DOI: 10.1002/prep.19860110104
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The Characteristic Temperature Method to Estimate Kinetic Parameters from DTA curves and to evaluate the compatibility of explosives

Abstract: The thermal analysis technique was used to rapidly evaluate the compatibility of explosives with contacted materials. The three kinetic parameters viz. activation energy E, reaction order n and pre‐exponential factor A were calculated from three characteristic temperatures of a single DTA curve. The compatibility was evaluated from the four parameters E, n and the characteristic temperatures Tm (peak maximum) and To (decomposition starting point on the DTA curve). The results are compared to those obtained fro… Show more

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Cited by 29 publications
(3 citation statements)
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“…The compatibility of 1,3,3-trinitroazetidine (TNAZ) with some energetic components and inert materials of solid propellants was successfully studied by using the PDSC method [17]. Actually, some energetic materials such as DNP will melt and volatilize without decomposition at ambient pressure [18] and it is likely to be unreasonable to judge the compatibility under that condition [19]. So in this work, the compatibilities of trans- 1,4,5,8-tetranitro-1,4,5,8-tetraazadecalin with some energetic components and inert materials under non-isothermal conditions investigated by means of pressure DSC [20][21][22][23][24] are reported.…”
Section: Introductionmentioning
confidence: 99%
“…The compatibility of 1,3,3-trinitroazetidine (TNAZ) with some energetic components and inert materials of solid propellants was successfully studied by using the PDSC method [17]. Actually, some energetic materials such as DNP will melt and volatilize without decomposition at ambient pressure [18] and it is likely to be unreasonable to judge the compatibility under that condition [19]. So in this work, the compatibilities of trans- 1,4,5,8-tetranitro-1,4,5,8-tetraazadecalin with some energetic components and inert materials under non-isothermal conditions investigated by means of pressure DSC [20][21][22][23][24] are reported.…”
Section: Introductionmentioning
confidence: 99%
“…The reactivity or compatibility of BHN with some energetic components and inert materials is one of the most aspects of BHN in practical application. There are a few reports on the synthesis, thermal decomposition, and its evolvements as combustion catalyst 7–11, seldom, the compatibility of BHN with some energetic components and inert materials used in propellants was reported.…”
Section: Introductionmentioning
confidence: 99%
“…Thermal analytical techniques such as DSC, TGA and (DTA), use small samples and mass measurement results are obtained in a short period of time [13][14][15]. However, these methods are suitable for testing explosives and pyrotechnic compositions.…”
Section: Introductionmentioning
confidence: 99%