The catalytic influence of benzoate and o-chlorobenzoate on the rate of complexation of chromium(III)

Linden, Willem J. van der; Ozinga, W.

doi:10.1007/bf01197237

Cited by 5 publications

(1 citation statement)

References 6 publications

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“…The reaction is slow and even under these conditions a 30-min boiling is required. Both benzoate and o-chlorobenzoate exert a catalytic effect on the rate of complexation which has been investigated by van der Linden and Ozinga (90). Benzoate at pH 4.0-4.5 and o-chlorobenzoate at pH 3.0-4.0 increase the reaction rate by a factor of 10-20; this allows shorter heating times and/or use of smaller excess of EDTA.…”

Section: Reactionsmentioning

confidence: 99%

Kinetic determinations and some kinetic aspects of analytical chemistry

Mottola¹,

Mark²

1982

Anal. Chem.

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KINETIC ASPECTS OF ANALYTICAL CHEMISTRYHoraclo A. Mottola was born in Buenos Aires, Argentina, and received undergraduate and graduate education at the University of Buenos Aires. He earned Licentiate and Doctoral degrees from the University of Buenos Aires and did predoctoral work with Professor Ernest B. Sandell at the University of Minnesota (Minneapolis). He spent two years at the University of Arizona (Tucson) as a postdoctoral research fellow In Professor Henry Freiser's research group. After teaching for two years at the University ot the Pacific (Stockton, CA), he joined OSU in the fall of 1967. Dr. Mottola's research interests include studies on the role of kinetics in analytical chemistry (including reaction reate determinations), analytical separations (solvent extraction and liquid-liquid chromatography), continuousflow analysis, and analytical application of photochromism.

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Section: Reactionsmentioning

confidence: 99%