The biomimetic deposition of carbonate apatite induced by titanium base calcium enriched silica films

Abstract

In order to obtain a fast biomimetic coating on titanium substrates, calcium enriched silica films were prepared on pure titanium substrates by sol–gel method under the following conditions: pH = 3 and the molar ratio of tetraethyl orthosilicate (TEOS)/H2O/EtOH/Ca2+ = 1∶4∶11∶0·08. The titanium base calcium enriched silica film is soaked in a slightly supersaturated Ca/P solution, with the concentration of calcium ion and phosphate group being 1·5 times of that of simulated body fluid, for seven days, a uniform apatite layer is precipitated onto the surfaces of calcium enriched silica films, which is quite rapidly. The investigation adopted SEM, EDX, Fourier transform infrared spectroscope and XRD to indicate that the coating was carbonate hydroxyapatite. The results show that it is a feasible way to obtain carbonate hydroxyapatite through functionalising the pure titanium substrates by preparing calcium enriched silica films on it from a sol–gel method.