The Behavior of Jordanian Oil Shale during Combustion Process from the El-Lajjun Deposit

Gougazeh, Mousa; Alsaqoor, Sameh; Borowski, Gabriel; Alsafasfeh, Ashraf; Hdaib, Ismail I.

doi:10.12911/22998993/150682

Cited by 1 publication

(1 citation statement)

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“…The peaks at these locations vary in intensity between the two samples, which is attributed to the discrepancies in the quartz and feldspar content as well as the types and quantities of the clay minerals. The peaks at 715 cm −1 and 1799 cm −1 and the peaks at 876 cm −1 and 1447 cm −1 are derived from calcites [34]. The peak at 1447 cm −1 in the MP samples also has the contribution of the deformation vibration peaks of methylene (-CH 2 -) [35].…”

Section: Thermogravimetric Analysismentioning

confidence: 92%

Thermogravimetric Pyrolysis Behavior and Kinetic Study of Two Different Organic-Rich Mudstones via Multiple Kinetic Methods

Li,

Zhou,

et al. 2023

Energies

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Two representative organic-rich mudstones from the Middle Permian (MP) and the Upper Carboniferous (UC) around the Fukang Depression in the Junggar Basin were selected to study and compare the pyrolysis behavior and kinetics. The MP and UC were described as type I and type II kerogen, respectively. The FTIR and XRD results revealed that the MP contains carbonates and different clay minerals compared to the UC. Peak deconvolution was used for the UC to delineate the pyrolysis process to better understand and compare the similarities and differences in the pyrolysis kinetics of the two mudstones. In addition, the Coats-Redfern method was employed to further differentiate the reaction stages based on the differences in the reaction models during pyrolysis. The kinetic results revealed that the activation energy, pre-exponential factors, and reaction models of the two mudstones have some similarities and differences. Combined with the analysis of the pyrolysis volatiles, the UC sample can release more CH4, CO, CO2, and aromatic hydrocarbon compounds at high temperatures, indicating that the UC has more oxygen-containing functional groups and aromatics, while the MP has more aliphatics. Through the above studies, the pyrolysis kinetics and mechanism of two organic-rich rocks could be clarified, guiding their development and efficient utilization.

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Section: Thermogravimetric Analysismentioning

confidence: 92%