On the other hand, in terms of the environmental impact, thermofluids such as RE347mcc, 42 RE245fa2 (HFEs) and R1234ze, R1233zd (HFOs) offer an attractive alternative, yet they 43 were neither the most efficient, nor generated the highest amount of net work output. This 44 paper provides thermofluids' selection guidelines to achieve maximum efficiency within 45 solar thermal energy technologies while keeping environmental impacts into considerations. 46