The application of ESR to evaluate the rate constants of chain growth in the polymerization of polyacrylate-esters

Korolev, G. V.; Smirnov, B.R.; Makhonina, L. I.

doi:10.1016/0032-3950(65)90542-3

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Homogeneous Chain-growth Polymerization1

Epr1

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1977

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Cited by 2 publications

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“…precipitation polymerization) are not well resolved 1195,1196). precipitation polymerization) are not well resolved 1195,1196).…”

Section: Homogeneous Chain-growth Polymerizationmentioning

confidence: 99%

ESR Spectroscopy in Polymer Research

Rånby¹,

Rabek²

1977

Polymers Properties and Applications

294

118

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“…precipitation polymerization) are not well resolved 1195,1196). precipitation polymerization) are not well resolved 1195,1196).…”

Section: Homogeneous Chain-growth Polymerizationmentioning

confidence: 99%

ESR Spectroscopy in Polymer Research

Rånby¹,

Rabek²

1977

Polymers Properties and Applications

294

118

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“…Free radicals R • in structured reaction media are characterized by long lifetimes (τ R ), which is why direct measurement of R • concentrations by the EPR method is possible for TFRP [3,6,[29][30][31][32][33][34][35][36][37][38][39][40][41][42][43]. The application of the EPR method appeared to be most effective for the following scientific directions: studying the kinetics of accumulation and decay of free radicals and structural and physical studies.…”

Section: Eprmentioning

confidence: 99%

Methods for Studying Three-Dimensional Free-Radical Polymerization and Cross-Linked Polymers

Korolev

Mogilevich

Three-Dimensional Free-Radical Polymerization

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Chapter 9 will be useful for those who are wishing to master the field of three-dimensional free-radical copolymerization because it contains a general description of applicability of various methods used in analytical and physical chemistry for specific tasks: studying the kinetics and peculiarities of cross-linked polymers formation using the TFRP method.Conventional and widely known methods for high-molecular compound chemistry that are described in detail in scientific publications are inapplicable for threedimensional free-radical polymerization (TFRP) with formation of cross-linked polymers because the reaction medium is strongly structured, starting from small degrees of conversion (from the gel point), and produces polymers are nonfusible and insoluble. Therefore, this chapter gives a brief description of well-proven experimental methods used to study TFRP kinetics and the mechanism as well as the structure and properties of cross-linked polymers.

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The application of ESR to evaluate the rate constants of chain growth in the polymerization of polyacrylate-esters

Cited by 2 publications

References 3 publications

ESR Spectroscopy in Polymer Research

ESR Spectroscopy in Polymer Research

Methods for Studying Three-Dimensional Free-Radical Polymerization and Cross-Linked Polymers

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