The electron energy distribution function (EEDF) in an afterglow of
a pulsed direct current discharge has been measured in an Ar:N2
mixture by means of a time-resolved Langmuir probe technique. The vibrational
temperature, Tv, of N2 molecules has also been experimentally
estimated. The results show that a correlation between an effective electron
temperature, Te, and Tv strongly varies with experimental conditions. In
particular the conditions exist under which the rapid decrease from high to
low Te values is observed at some moment after the discharge pulse, while
the vibrational temperature remains almost constant.
The theoretical study of the EEDF in Ar:N2 afterglow plasma has
also been made by the numerical solution of an appropriate Boltzmann equation
by taking into account electron-electron collisions as well as superelastic
vibrational and superelastic electronic collisions. Calculations show that for
a given Tv the value of Te depends on the electron concentration, ne.
Moreover, the ranges of ne and Tv exist, where two different solutions of
Boltzmann equations can be obtained.
Finally, the comparison of the theoretical and experimental results is
performed and an explanation of the experimentally observed phenomenon is given.