The Alkoxides of Molybdenum, Tungsten and Vanadium and their
                        Hydrolysis Products

Kessler, Vadim G.; Turevskaya, E. P.; Kucheiko, S.I.; Kozlova, N. I.; Turova, Nataliya; Obvintseva, I. E.; Yanovskaya, M. I.

doi:10.1557/proc-346-3

Cited by 5 publications

(5 citation statements)

References 17 publications

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“…Co, Ni, Fe, Ga, Sc, Y, Ge. Ti, Zr, Nb, and Ta alkoxides were produced with current efficiencies higher than 64%. − …”

Section: Electrochemical Synthesis Of Sol−gel Precursorsmentioning

confidence: 99%

“…Ti, Zr, Nb, and Ta alkoxides were produced with current efficiencies higher than 64%. [329][330][331][332] The reaction mechanism of alkoxide formation from metal anodes was suggested by Lehmkuhl and coworkers. 331 The process is comprised of anodic dissolution of the metal and formation of the corresponding halogenide MX n .…”

Section: Electrochemical Synthesis Of Sol-gel Precursorsmentioning

confidence: 99%

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Sol−Gel Materials in Electrochemistry

et al. 1997

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The subject of sol-gel electrochemistry is introduced, starting with a brief account of milestones in its evolution. Then, the types of sol-gel materials that are useful for electrochemistry are presented, followed by a description of recent advances in the various fields of sol-gel electrochemistry. Modified electrodes, solid electrolytes, electrochromic devices, and corrosion protection coatings are described. Emerging fields such as RuO 2 supercapacitors and electrochemical synthesis of sol-gel precursors are also addressed.

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“…Co, Ni, Fe, Ga, Sc, Y, Ge. Ti, Zr, Nb, and Ta alkoxides were produced with current efficiencies higher than 64%. − …”

Section: Electrochemical Synthesis Of Sol−gel Precursorsmentioning

confidence: 99%

Section: Electrochemical Synthesis Of Sol-gel Precursorsmentioning

confidence: 99%

Sol−Gel Materials in Electrochemistry

et al. 1997

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“…The evacuation of all these three solutions gave waxy solids, which were studied by IR and it was found that their spectra coincided in all the essential details with each other and that of La2MoaOs(OPr/)14 (450-460w, 603 v.s. sharp, 830 s, 840 s, 960 sbr, 990 sbr, see also [3] for details), thus indicating the existence of a stable La2Mo4Os core in all the three solutions.…”

Section: Resultsmentioning

confidence: 78%

“…The heterometallic LiMo204(OPr/)5 (i PrOH) and La2Mo4Os(OPr i)14 derivatives were synthesized as earlier described in the literature [3]. The solubility isotherm (25~ in the system LiORMoO2(OR)2-ROH (R=C2H4OMe) was studied by analytical methods.…”

Section: Methodsmentioning

confidence: 99%

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Solution stoichiometry control for pure LiLaMo2O8 phases in sol-gel preparation

Kessler

Panov

Turova

et al. 1997

J Sol-Gel Sci Technol

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Abstract. The hydrolysis of solutions, containing either LiMo204(OPr/)5(iPrOH) and "La(OPr/)3 '' or LiOPr / and La2Mo4Os(OPr/)14 in 1 : 1 ratio, in toluene or ipIOH, by water solutions in isopropanol, leads to formation of monolythic gels. The latter can be converted by drying and heat treatment at 600~ into a fine powder of pure ot-LiLaMo208 phase, which is transformed into fl-LiLaMo2Os powder by annealing at 800~ The sintering of the pellets pressed under 4 bar pressure of ot-LiLaM0208 powder at 800~ for 2 h converts them into pieces of /3-LiLaMo2Os transparent ceramics, thus providing a route to LiLnM0208 laser waveguide materials.

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