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Potential differences have been measured between the alkali metals and their dilute amalgams in propylene carbonate solutions. Similar behavior of potential drift in nonaqueous cells was observed in PC (1, 21), DMSO (22,23), DMF (24), and N-MF (25). The emf values measured are in satisfactory agreement with those obtained earlier in other solvents.
In the course of our studies on the thermodynamic properties (1, 2) and the kinetic measurements (3) of the alkali metals in aluminum chloride-propylene carbonate (PC) solution, we have measured the poten-* Electrochemical Society Active Member.
Key words: lithium amalgam, sodium amalgam, potassium amalgam, rubidium amalgam, cesium amalgam, propylene carbonate.
Potential differences have been measured between the alkali metals and their dilute amalgams in propylene carbonate solutions. Similar behavior of potential drift in nonaqueous cells was observed in PC (1, 21), DMSO (22,23), DMF (24), and N-MF (25). The emf values measured are in satisfactory agreement with those obtained earlier in other solvents.
In the course of our studies on the thermodynamic properties (1, 2) and the kinetic measurements (3) of the alkali metals in aluminum chloride-propylene carbonate (PC) solution, we have measured the poten-* Electrochemical Society Active Member.
Key words: lithium amalgam, sodium amalgam, potassium amalgam, rubidium amalgam, cesium amalgam, propylene carbonate.