The 23Δg State of 7Li2

The molecular dissociation energies of some electronic states of hydride and N 2 molecules were studied using a parameter-free analytical formula suggested in this study and the algebraic method (AM) proposed recently. The results show that the accurate AM dissociation energies D e AM agree excellently with experimental dissociation energies D e expt , and that the dissociation energy of an electronic state such as the 2 3 Δ g state of 7 Li 2 whose experimental value is not available can be predicted using the new formula.algebraic method, diatomic molecule, vibrational energy, dissociation energy

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“…7848.1992 a) From ref. [27]; b) Calculated using eq. (16) and the highest three vibrational energies from algebraic method (AM).…”

Section: Application and Discussionmentioning

confidence: 99%

Accurate studies on dissociation energies of diatomic molecules

2007

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“…The pulsed PFOODR experimental setup was reported in a recent publication (8). Natural lithium vapor was generated in a crossed heatpipe with about 1 Torr argon buffer gas (corresponding to about 700°C).…”

Section: Methodsmentioning

confidence: 99%

The Predissociation of the 13Σ−g State of 7Li2

Dai

Liu

et al. 2001

Journal of Molecular Spectroscopy

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“…The experimental setup has been described earlier (5) and will be only briefly summarized here. Natural lithium metal (92.57% 7 Li and 7.43% 6 Li) was heated in a crossed heatpipe oven with about 1 Torr argon buffer gas.…”

Section: Methodsmentioning

confidence: 99%

“…(14). 5. Compare the eigenvalues calculated with the RKR potential curve with the observed term values.…”

Section: Experimental Data and Analysismentioning

confidence: 99%

“…We calculated the quantum defect of these two states again according to the molecular Rydberg equation, IP − E n * = /(n − δ) 2 , [5] where IP is the ionization energy, is the Rydberg constant, (n − δ) = n * is the effective principal quantum number, and δ = n − n * is the quantum defect. The T e of the 5 1 + g state is 33 319.6 cm −1 , n * = 3.657, δ = 0.343.…”

Section: Experimental Data and Analysismentioning

confidence: 99%

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