Th-Symmetrical Hexakisadducts of C60 with a Densely Packed π-Donor Shell Can Act as Energy- or Electron-Transducing Systems

Diekers, Michael; Luo, Chuping; Guldi, Dirk M.; Hirsch, Andreas

doi:10.1002/1521-3765(20020215)8:4<979::aid-chem979>3.0.co;2-6

Cited by 31 publications

(13 citation statements)

References 81 publications

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“…Upon the removal of THF from the organic phase on a rotary evaporator, the precipitate was collected and purified on a silica gel column with chloroform as eluent to obtain 8 as colorless powders (1.03 g, 84% yield). 1 H NMR (500 MHz, CDCl 3 ) *: 8.20~8.10 (m, 6H), 8.08 (d, J = 7.5 Hz, 4H), 8.01~7.97 (m, 6H), 7.95 (d, J = 7.5 Hz, 2H), 4.19 (t, J = 6.5 Hz, 4H), 3.39 (s, 2H), 3.29 (t, J = 7.5 Hz, 4H), 1.87~1.86 (m, 4H), 1.79~1.76 (m, 4H) ppm; 13 3073 9% 13…”

Section: Bis(pyrenebutyl) Malonate (8)mentioning

confidence: 99%

Simple Modification in Hexakis-Addition for Efficient Synthesis of C₆₀-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores

Kitaygorodskiy

Carino

et al. 2005

Org. Lett.

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Section: Bis(pyrenebutyl) Malonate (8)mentioning

confidence: 99%

Simple Modification in Hexakis-Addition for Efficient Synthesis of C₆₀-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores

Kitaygorodskiy

Carino

et al. 2005

Org. Lett.

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“…1. The figure shows a pattern of hexakis-adducts of C 60 as well as two monomers that have been synthesised experimentally by the regioselective mild Bingel reaction or tether-directed remote functionalisation [24][25][26][27]. Monomers of this type could be polymerised.…”

Section: Resultsmentioning

confidence: 99%

Molecular design of fullerene‐based ultralow‐k dielectrics

Wang

Seifert

Hermann

2006

Physica Status Solidi (a)

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This paper presents results of a theoretical study of hypothetical insulating layers for semi-conducting circuits. The dielectric material consists of C 60 fullerenes interconnected by bridge molecules. The structural optimisation is carried out using quantum-chemical methods. The predicted materials have ultralow values of the static dielectric constant of about 1 5 k = . and good elastic bulk moduli of 12 B = to 17 GPa. These values meet the demands of future microelectronic devices.

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“…MAPS was synthesized according to the literature with little modication. 26 9,10-Bis(3-hydroxypropyloxy)anthracene (0.4 g, 1.22 mmol) and pyridine (0.1 g, 1.22 mmol) were dissolved in dry CH 2 Cl 2 (100 mL), then stearyl chloride (0.185 g, 0.61 mmol) was added dropwise to the solution under a nitrogen atmosphere. The mixture was stirred at room temperature for 2 hours.…”

Section: Modication Of Chms With Uorescent Dye Ritc (Crhms)mentioning

confidence: 99%

Visible-light degradable polymer coated hollow mesoporous silica nanoparticles for controlled drug release and cell imaging

Yang

Chen

et al. 2013

J. Mater. Chem. B

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A core-shell nanocomposite based on photo-degradable polymer coated hollow mesoporous silica nanoparticles (HMS) was successfully prepared for targeted drug delivery and visible-light triggered release, as well as fluorescence cell imaging. The HMS nanoparticles were first modified by the longchain hydrocarbon octadecyltrimethoxysilane (C18) and fluorescent agent Rhodamine B isothiocyanate (RITC), and then encapsulated by a photodegradable amphiphilic copolymer via a self-assembly process.The obtained nanocarrier showed a high drug loading content due to the hollow core and mesopores of the HMS and could target folic acid receptor over-expressed tumor cells efficiently for conjugating folic acid (FA) in the amphiphilic polymer. The drug release could be triggered by the irradiation of green light (500-540 nm) due to the photodegradation of amphiphilic copolymer coated on the HMS. Furthermore, the targeted drug delivery and controlled release processes could be tracked by fluorescence imaging for the doping of RITC on the HMS. The In vitro results suggested that a smart visible light responsive drug delivery system was successfully prepared for the potential applications of cancer diagnosis and therapy.

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Th-Symmetrical Hexakisadducts of C60 with a Densely Packed π-Donor Shell Can Act as Energy- or Electron-Transducing Systems

Cited by 31 publications

References 81 publications

Simple Modification in Hexakis-Addition for Efficient Synthesis of C₆₀-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores

Simple Modification in Hexakis-Addition for Efficient Synthesis of C₆₀-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores

Molecular design of fullerene‐based ultralow‐k dielectrics

Visible-light degradable polymer coated hollow mesoporous silica nanoparticles for controlled drug release and cell imaging

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Th-Symmetrical Hexakisadducts of C60 with a Densely Packed π-Donor Shell Can Act as Energy- or Electron-Transducing Systems

Cited by 31 publications

References 81 publications

Simple Modification in Hexakis-Addition for Efficient Synthesis of C60-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores

Simple Modification in Hexakis-Addition for Efficient Synthesis of C60-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores

Molecular design of fullerene‐based ultralow‐k dielectrics

Visible-light degradable polymer coated hollow mesoporous silica nanoparticles for controlled drug release and cell imaging

Contact Info

Product

Resources

About

Simple Modification in Hexakis-Addition for Efficient Synthesis of C₆₀-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores

Simple Modification in Hexakis-Addition for Efficient Synthesis of C₆₀-Centered Dendritic Molecules Bearing Multiple Aromatic Chromophores