Tetraphosphorus Hexamethylimide Trisulfide-Borane and Nickel Tricarbonyl Adducts

Abstract

P4(NMe) S reacts with B2H6 and Ni(CO)4 to yield P4(NMe)6S3BH3No reaction was observed with 6 3 and P4(NMe)6S3Ni(C0)3, respectively.

(PNSiMe3)4(NMe)6: A robust tetravalent phosphaza-adamantane scaffold for molecular and macromolecular chemistry

“…[23][24][25][26] Their quantitative, one-step, multi-gram synthesis from commodity reagents (PCl3, RNH2) is appealing from a practical perspective, and their high molecular symmetry makes them inherently suited for evolving a four-directional functional platform. Quadruple oxidation of some derivatives of C with azides, sulfur, and oxygen has also been reported, [27][28][29][30][31][32] but no subsequent reactivity was possible since the resulting compounds do not feature sufficiently labile bonds. Salts of the binary polyanion P4N6 10-have also been reported, but their high temperature solid-state synthesis (>600 o C elemental melt) and insolubility have precluded further use in synthetic chemistry.…”

(PNSiMe3)4(NMe)6: A robust tetravalent phosphaza-adamantane scaffold for molecular and macromolecular chemistry

“…[23][24][25][26] Their quantitative, one-step, multi-gram synthesis from commodity reagents (PCl3, RNH2) is appealing from a practical perspective, and their high molecular symmetry makes them inherently suited for evolving a four-directional functional platform. Quadruple oxidation of some derivatives of C with azides, sulfur, and oxygen has also been reported, [27][28][29][30][31][32] but no subsequent reactivity was possible since the resulting compounds do not feature sufficiently labile bonds. Salts of the binary polyanion P4N6 10have also been reported, but their high temperature solid-state synthesis (>600 o C elemental melt) and insolubility have precluded further use in synthetic chemistry.…”