Tetranuclear dioxomolybdenum (VI) cluster anion, hydrogen bond interaction with 1,2-di(4-pyridyl)ethylene

Alghool, Samir; Slebodnick, Carla

doi:10.1007/s10973-015-5211-y

Cited by 3 publications

(1 citation statement)

References 46 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It is known that the trans ‐ isomer of the DPE molecule included in the walls of the “breathing” mesoporous organosilicon material under photoirradiation isomerizes into the cis ‐isomer that leads to an abrupt increase in the area and volume of the pores of the material (16). DPE has also been used to create a tetranuclear molybdenum(VI) dioxide cluster (17). In order to understand the processes, which occur in materials containing DPE, it is necessary to study the processes which occur in pure DPE under light irradiation.…”

Section: Introductionmentioning

confidence: 99%

Photoisomerization of 1,2‐Di(4‐pyridyl)ethylene According to NMR and UV Spectroscopy Data and Density Functional Modeling

Shaidullina

Sharipova

Volkov

et al. 2023

Photochem & Photobiology

View full text Add to dashboard Cite

Photoisomerization of 1,2‐di(4‐pyridyl)ethylene under UV irradiation was studied by NMR and UV spectroscopy in solutions of acetone, acetonitrile and chloroform. It has been established that in the studied solutions under irradiation, geometric photoisomerization occurs: the trans‐isomer transforms into the cis‐isomer and then cyclization occurs. DFT modeling of the listed processes, states and UV absorption spectra of the sample in an acetonitrile solution was performed.

show abstract

Section: Introductionmentioning

confidence: 99%

Photoisomerization of 1,2‐Di(4‐pyridyl)ethylene According to NMR and UV Spectroscopy Data and Density Functional Modeling

Shaidullina

Sharipova

Volkov

et al. 2023

Photochem & Photobiology

View full text Add to dashboard Cite

show abstract

A cucurbit[8]uril-based fluorescent probe for the selective detection of pymetrozine

Shan,

Pan,

Chen

et al. 2023

Journal of Molecular Structure

View full text Add to dashboard Cite

Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe⁺) ligand in metal-driven supramolecular assembly: a comprehensive structural review

Singha,

Datta,

Halder

et al. 2024

Reviews in Inorganic Chemistry

View full text Add to dashboard Cite

A protonated form of 1,2-bis(4-pyridyl)ethylene (HBpe+), produced through proton transfer or pH adjustments, plays a significant role in forming unique supramolecular structures. In contrast, non-protonated forms of the molecule (Bpe) are extensively studied in metal-organic complexes. In this review, we examine the fascinating world of HBpe+ as a monodentate ligand in the realm of coordination chemistry. It discusses how protonated ligands influence the assembly of supramolecular structures, as well as their properties and functions. Structures such as 1:1 adduct, coordination polymers, and metal clusters are often formed as a result. In these assemblies, HBpe+ engages in a variety of interactions that influence its supramolecular behavior. The interactions include coordination complexes with metal ions, hydrogen bonds, aromatic ring stacking, and double bond stacking (π⋯π stacking). The flexibility and conformation of the ligand have a significant impact on the overall structure and stability of complexes. It opens the door to developing functional materials by unraveling the unique attributes and role of HBpe+ in supramolecular assembly. With these insights, it is possible to explore the functional properties of HBpe+ through controlled assembly processes in order to create innovative and functional materials.

show abstract

Tetranuclear dioxomolybdenum (VI) cluster anion, hydrogen bond interaction with 1,2-di(4-pyridyl)ethylene

Cited by 3 publications

References 46 publications

Photoisomerization of 1,2‐Di(4‐pyridyl)ethylene According to NMR and UV Spectroscopy Data and Density Functional Modeling

Photoisomerization of 1,2‐Di(4‐pyridyl)ethylene According to NMR and UV Spectroscopy Data and Density Functional Modeling

A cucurbit[8]uril-based fluorescent probe for the selective detection of pymetrozine

Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe⁺) ligand in metal-driven supramolecular assembly: a comprehensive structural review

Contact Info

Product

Resources

About

Tetranuclear dioxomolybdenum (VI) cluster anion, hydrogen bond interaction with 1,2-di(4-pyridyl)ethylene

Cited by 3 publications

References 46 publications

Photoisomerization of 1,2‐Di(4‐pyridyl)ethylene According to NMR and UV Spectroscopy Data and Density Functional Modeling

Photoisomerization of 1,2‐Di(4‐pyridyl)ethylene According to NMR and UV Spectroscopy Data and Density Functional Modeling

A cucurbit[8]uril-based fluorescent probe for the selective detection of pymetrozine

Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe+) ligand in metal-driven supramolecular assembly: a comprehensive structural review

Contact Info

Product

Resources

About

Unveiling the multifaceted roles of protonated 1,2-bis(4-pyridyl)ethylene (HBpe⁺) ligand in metal-driven supramolecular assembly: a comprehensive structural review