Tetrakis(dimethylamido)zirconium(IV)

Tethered Bis(amidate) and Bis(ureate) Supported Zirconium Precatalysts for the Intramolecular Hydroamination of Aminoalkenes

“…One such reaction, hydroamination, generates new C–N bonds, while avoiding the use of protecting groups and stoichiometric co‐reagents 2. Catalysts based on zirconium have shown promising reactivity3 and are particularly attractive due to their reduced cost and low toxicity 4. Recent advances in Zr hydroamination catalyst development have focused on ligand design, including tethered bidentate amidate5 and ureate ligands 6.…”