Abstract:Chiral multi‐resonance thermally activated delayed fluorescence (CP‐MR‐TADF) materials hold promise for circularly polarized organic light‐emitting diode (CP‐OLED) and 3D display. Herein, we present two pairs of tetraborated intrinsically axial CP‐MR‐TADF materials, R/S‐BDBF‐BOH and R/S‐BDBT‐BOH, with conjugation‐extended bidibenzo[b,d]furan and bidibenzo[b,d]thiophene as chiral sources, which effectively participate in the distribution of frontier molecular orbitals. Due to the heavy‐atom effect, sulfur atoms… Show more
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