“…Carbon dioxide dissolved in aquifer water at the CO 2 -water interface increases water density in the order of 1% and, depending on aquifer characteristics, sinks to the bottom of the aquifer due to gravitational instability and convective mixing if certain conditions are being met (see, e.g., Paterson, 2007 andKneafsey andPruess, 2010; and also the review paper by Emami-Meybodi et al, 2015, this issue). Solubility trapping is limited in the case of relatively thick CO 2 plumes in thin aquifers (h/H > O(0.01), where h and H are, respectively, plume and aquifer thicknesses; Espie and Woods, 2014). In addition, CO 2 solubility depends on in situ conditions, increasing with increasing pressure and decreasing with increasing temperature and salinity (see Span and Wagner, 1996;Enick and Klara, 1990;Spycher and Pruess, 2005), such that, depending on the in situ conditions of the storage site, it is likely insignificant during the injection phase of a CO 2 storage operation and only in the order of a few percent for periods of time relevant for CO 2 trapping at irreducible saturation and plume immobilization (Espie and Woods, 2014).…”