Phasor Measuring Units (PMU) is considered as a feasible alternative for power system data communication and for the preparation of smart grid. To operate multiple PMUs in stable mode, synchronization is a much essential procedure. After examining the concise literature survey on topical PMU applications, this paper step ahead by considering prevailing objectives such as: extension of network topology and PMU calibration considering bias errors. The appropriate deployment of PMUs and intimidating situation influence the reliance on physical configuration. Hence, it is obligatory to extend the topology of the networks. Also, calibrating the PMUs in a definite trail is crucial as the phasor measurements will be corrupted by bias error. This paper proposes a novel framework for bias error detection and calibration of PMU while expanding the topology network. With a whale optimization algorithm based method to improve the accuracy of PMU measurements for enhancing power system state estimation, monitoring and control operations. Case studies on the standard test systems have been conducted to test the efficacy of the intended tool.